What is Flash Mixer in Water Treatment Plant?

What is Flash Mixer in Water Treatment Plant?

Main use of Flash mixer

  1. To dose the polymer
  2. To mix the treated effluent after EC with polymer
  3. To increase the fast settlement in HRSCC
  4. To remove the Hydrogen (H2) gas this is released from EC process due to reaction.
  5. To increase flock size to bigger

STRENGTH OF HYDROCHLORIC ACID

BURETTE

0.1 N Sodium hydroxide solution

SAMPLE PREPARATION

Take 10 gm of HCl in standard flask and make up to 500 ml using neutral water

CONICAL FLASK

  • 10ml of above diluted sample
  • 2-3drops Phenolphthalein indicator

TITRATION

0.1N Sodium hydroxide Vs Dilute hydrochloric acid

ENDPOINT

Appearance of pink color

CALCULATION

 Strength of Hydrochloric acid =    Titrate value x 0.1 x 36.47 x500 x 100

                                                               Weight of HCL x 10 x 1000

                                                    =     Titrate value x 1.82 %

STRENGTH OF SODIUM HYDROXIDE

BURETTE

0.1 N Hydrochloric acid.

SAMPLE PREPARATION

 Take 2 gm of caustic dissolved In 250 ml  distilled water

CONICAL FLASK

  • 25 ml of above diluted sample
  • 2-3drops Phenolphthalein indicator
  • The solution turns pink

TITRATION

0.1N Hydrochloric acid Vs Dilute sodium hydroxide

ENDPOINT

Disappearance of pink color

CALCULATION

 Strength of Sodium hydroxide =    Titrate value x 0.1 x 40 x 250 x 100

                                                               Weight of NaoH x 25 x 1000                                                                                                

                                                   =    (Titrate value x 0.1 x 40) / 2

=    (Titrate value x 4) / 2

=    Titrate value x 2                                                              

 STRENGTH OF SODIUM CARBONATE

BURETTE

0.1 N Hydrochloric acid.

SAMPLE PREPARATION

 Take 2 gm of Soda ash dissolved  In 250 ml  distilled water

CONICAL FLASK

  • 5 ml of above diluted sample
  • 2-3 drops Methyl Orange indicator
  • The solution turns Golden yellow

TITRATION

0.1N hydrochloric acid Vs Dilute sodium carbonate

ENDPOINT

Appearance of Red Orange color

CALCULATION

Strength of Sodium carbonate =    Titrate value x 0.1 x 53 x 250 x 100

                                                               Weight of Na2CO3 x 25 x 1000                                                                                           

=    (Titrate value x 0.1 x 53) / 2

=    (Titrate value x5.3) / 2

=    Titrate value x 2.65                                                     

STRENGTH OF ACETIC ACID

BURETTE

0.1 N Sodium Hydroxide

SAMPLE PREPARATION

 Take 2 gm of Acetic acid dissolved  In 250 ml  distilled water

CONICAL FLASK

  • 25 ml of above diluted sample
  • 2-3 drops Phenolphthalein indicator
  • No color change

TITRATION

0.1N Sodium hydroxide Vs Dilute acetic acid

ENDPOINT

Appearance of pink color

CALCULATION

Strength of Acetic  acid           =    Titrate value x 0.1 x 60 x 250 x 100

                                                           Weight of CH3COOHx 25 x 1000                                                                                           

                                                   =    (Titrate value x 0.1 x 60) / 2

=    (Titrate value x 6) / 2

=    Titrate value x 3                                                              

STRENGTH OF SULFURIC ACID

BURETTE

0.1 N Sodium hydroxide

SAMPLE PREPARATION

 Take 2 gm of Sulfuric acid dissolved  In 250 ml  distilled water

CONICAL FLASK

  • 25 ml of above diluted sample
  • 2-3 drops Phenolphthalein indicator
  • No color change

TITRATION

0.1N Sodium hydroxide Vs Dilute sulfuric acid

ENDPOINT

Appearance of pink color

CALCULATION

 Strength of Sulfuric  acid         =    Titrate value x 0.1 x 49 x 250 x 100

                                                               Weight of H2SO4 x 25 x 1000                                                                                             

                                                   =    (Titrate value x 0.1 x 49 / 2

=    (Titrate value x 4.9) / 2

                                                   =    Titrate value x 2.45 

    STRENGTH OF HYDROGEN PEROXIDE

BURETTE

0.1 N Potassium permanganate

SAMPLE PREPARATION

  • Take 5 gm of H2O2 dissolved  In 250 ml  distilled water

CONICAL FLASK

  • 25 ml of above diluted sample
  • 20 ml of 2N Sulfuric acid
  • 30 ml of distilled water

TITRATION

0.1 N Potassium permanganate Vs Dilute hydrogen peroxide

ENDPOINT

Appearance of pink color

CALCULATION

Strength of Hydrogen peroxide =    Titrate value x 0.1 x 17x 250 x 100

                                                               Weight of H2O2 x 25 x 1000                                                                                                

                                                     =    (Titrate value x 0.1 x 17)/ 5

=    (Titrate value x 1.7) / 5

=    Titrate value x 0.34

STRENGTH OF SODIUM BI SULFITE

SAMPLE PREPARATION

  • Take 2gm of sodium bi sulfite dissolved  In 250 ml  distilled water

TITRATION

 

 

S.NO

 

 

 

BLANK

 

 

SAMPLE

 

 

Burette

 

 

0.1 N Sodium thio sulfate

 

 

 

0.1 N Sodium thio sulfate

 

 

Conical flask

 

 

25 ml distilled water + 50 ml iodine solution

 

 

25 ml diluted sample + 50 ml iodine solution

 

 

Titration

 

 

Titrate  up to the appearance of light yellow

 

 

Titrate  up to the appearance of light yellow

 

 

Indicator

 

 

Add starch- blue color appears

 

 

Add starch- blue color appears

 

 

 

Titration

 

 

Continue with 0.1 N Sodium thio sulfate

 

 

 

Continue with 0.1 N Sodium thio sulfate

 

 

 

End point

 

 

Disappearance of blue color

 

 

Disappearance of blue color

 

 

 

Titration value

 

 

A

 

 

B

 

CALCULATION

Strength of Sodium bi sulfite =    5.205 X (A – B)

2

=     2.602 X (A – B)

 STRENGTH OF SODIUM SULFATE

SAMPLE PREPARATION

  • Take 8gm of sodium sulfate dissolved  In 250 ml  distilled water

ROCEDURE

In a clean 250 ml beaker 25 ml of diluted sample and 5 ml of Hydrochloric acid is added and

mix properly. Then 25 ml of 10% Barium chloride solution is added with stirring . The solution is boiled with 50 ml of distilled water for 15 min and kept for at least 6 hours. The precipitate is filtered through a gooch crucible and washed with hot distilled water for several times  to remove chlorides and dried  to constant weight at 105^C.

CALCULATION

Strength of Sodium sulfate   = (608.6 X Wt. of the precipitate) / 8

        STRENGTH OF SODIUM SILICATE

BURETTE

0.1 N Hydrochloric acid

SAMPLE PREPARAT

  • Take 2gm of sodium silicate dissolved  In 250 ml  distilled water

CONICAL FLASK

  • 25 ml  of above diluted sample
  • 2-3 drops of Methyl orange indicator

TITRATION

0.1 N Hydrochloric acid Vs Dilute sodium silicate

ENDPOINT

Appearance of red orange

  • Then the solution in the conical flask is treated with 5 ml of concentrated Hydrochloric acid and is evaporated to dryness.
  • The residue is again treated with 5 ml of concentrated Hydrochloric acid and once again evaporated to dryness.
  • This residue is filtered through a What Mann No .40 filter paper and washed with hot distilled water for several times to remove soluble impurities.
  • Then the filter paper is ignited in a weighed silica crucible . After ignited

STRENGTH OF SODIUM  SULFIDE

SAMPLE PREPARATION

  • Take 2gm of sodium sulfide dissolved  In 250 ml  distilled water

SAMPLE -A

In a 250 ml beaker 25 ml of diluted sample and 25 ml of 20 % Zinc sulfate solution are taken. The mix is stirred well. The precipitate is filtered through a filter paper and the filtrate is collected in a conical flask. The precipitate is washed with water and the washings are also added to the conical flask.

TITRATION

 

 

S.NO

 

 

 

SAMPLE

 

 

SAMPLE – A

 

 

Burette

 

 

0.1 N Iodine solution

 

 

 

0.1 N Iodine solution

 

 

 

Conical flask

 

 

25 ml diluted sample

 

 

Sample – A

 

 

Titration

 

 

Titrate  up to the appearance of light yellow

 

 

Titrate  up to the appearance of light yellow

 

 

Indicator

 

 

Add starch- blue color appears

 

 

Add starch- blue color appears

 

 

 

Titration

 

 

Continue with 0.1 N Iodine solution

 

 

 

 

Continue with 0.1 N Iodine solution

 

 

 

 

End point

 

 

Disappearance of blue color

 

 

Disappearance of blue color

 

 

 

Titration value

 

 

A

 

 

B

 

CALCULATION

Strength of Sodium bi sulfite =    (3.903 X (A – B))/2

STRENGTH OF SODIUM ACETATE

 BURETTE

0.1 N Hydrochloric acid.

SAMPLE PREPARATION

  • Take 5gm of Sodium acetate
  • CONICAL FLASK
  • 25 ml of above diluted sample
  • 3 drops Methyl Orange indicator
  • The solution turns Golden yellow

TITRATION

0.1N Hydrochloric acid Vs Dilute sodium acetate

ENDPOINT

Appearance of Red Orange color

CALCULATION

Strength of Sodium acetate    =     Titrate value x 0.1 x 136x 250 x 100

                                                          Weight of CH3COONa.3H2O x 25 x 1000                                                                                            

=    (Titrate value x 0.1 x 136) / 5

=    (Titrate value x13.6) / 5

=    Titrate value x   2.72                                                 

STRENGTH OF ALUMINIUM SULFATE

SAMPLE PREPARATION

  • Take 10gm of sodium sulfate dissolved  In 250 ml  distilled water

PROCEDURE

In a clean 500 ml beaker 25 ml of diluted sample and 50 ml of 10 % Ammonium chloride solution, 150 ml of distilled water and 2 drops of methyl red indicator solution are added. The solution is heated just to boiling and 10% ammonium liquor solution is added till the color changed to distinct yellow. After again boiling for 2 min, the precipitate of aluminium

hydroxide is filtered when hot , washed with hot ammonium nitrate solution and ignited in a muffle furnace  to constant weight in a porcelain crucible . the ash is cooled in a desiccators and weighed.

CALCULATION

Strength of aluminum sulfate   = (6537 X Wt. of the Ash) / 10

 STRENGTH OF SODIUM NITRITE

BURETTE

0.1 N Potassium permanganate

SAMPLE PREPARATION

  • Take 2 gm of NaNO2 dissolved  In 250 ml  distilled water

CONICAL FLASK

  • 25 ml of above diluted sample
  • 20 ml of 2N Sulfuric acid
  • Heat up to 60 ^ C

TITRATION

0.1 N Potassium permanganate Vs Dilute sodium nitrite

ENDPOINT

Appearance of pink color

CALCULATION

Strength of sodium nitrite                 =    Titrate value x 0.1 x 34.51x 250 x 100

                                                                       Weight of NaNO2x 25 x 1000                                                                                                   

                                                             =    (Titrate value x 0.1 x 34.51)/ 2

=    (Titrate value x 3.451) / 2

=    Titrate value x 1.7255

What is Bar Screen? Screening Water Treatment Process.

What is Bar Screen? Screening Water Treatment Process.

Bar Screen

Bar screen and screening water treatment is the first process unit operation used at wastewater treatment plants. Screening removes objects such as rags, paper, plastics and metals to prevent damage and clogging of downstream equipment and piping.Cleaning frequency depends on the characteristics of the wastewater entering a plant.

Bar Screen Operation and maintenance considerations

  • Check and clean the bar screen at frequent intervals.
  • Do not allow solids to overflow /escape from the screen bar screen
  • Ensure no large gaps are formed due to the breakage of the screening water treatment.
  • Replace breakage bar screen immediately.
  • Mechanically cleaned screening system to remove larger materials because they reduce labor cost and they improve flow conditions and screening capture.
  • Mechanically cleaned bar screen should have a standby screen to put in operation when the primary screening device is out of service.

Trouble Shooting of screening water treatment

S.NOPROBLEMCAUSE
1Large particles pass through and check the pumpsPoor operation /screen damaged
2Up stream water levels is much higher than down stream levelPoor operation (inadequate cleaning)
3Excessive collection of trash on screening water treatmentPoor operation
4Excessive odorPoor operation /trash disposal practices.

Daily and weekly maintenance work

  • Check gear box oil qty periodically and completely drain out oil and replace afresh as per manufacture’s recommendation.
  • Check oil pump every day ,top up if necessary
  • Check every day chain alignments and must periodically 4 hrs once chain cleaned or removed impurities materials.

Main use of screening water treatment

  • To remove the suspended solids
  • To avoided the pump cloaking
  • To increase the Bacteria attachment in the FBBR system
  • To reduce the Sludge Quantity in filter press
  • To Reduce the short-circuit in Electro Coagulation System
  • To avoided the solids cloaking in the air distribution system in Equalization tank
  • To increase the air volume in Equalization tank

Project Brief of screening water treatment plant

Auto  is engaged into printing of textile garments using pigments and reactive colours.  The Effluent Treatment Plant is designed to treat 40m3 per day of the effluent to achieve the norms prescribed by the local governing bodies and BSR guidelines. The Factory presently produce only up to 10m3/Day Effluent. The ETP is designed for higher capacity considering the future expansion and addition of Washing Process.

Plan Capacity of screening water treatment plant

The Effluent screening water treatment Plant is designed to treat wastewater generated from the processing unit. The Effluent treatment plant is designed to treat 40m3/day of Washing & Printing combined effluent generated from the process house (Washing 15m3/Day & Printing 5m3/Day).     The plant will be capable of operating at the flow rate of 2m3/hr. The Present Effluent generation is 10m3/Day and the Plant is operated for 10-12 Hours per Day with 50% flow rate.

Conclusion

The treatment plant is based on Electro-coagulation Treatment. Electrocoagulation system has distinct advantages for the treatment of Textiles   industrial wastewater. EC Systems present high efficiency, easy operation and environmental compatibility this process involves generation of coagulants by electrolytic oxidation of a sacrificial anode (iron) by applying a direct current. The most widely used electrode materials in electrocoagulation process are  iron. The hydrolyzed iron  ions can form long chains of Fe-O-Fe-OH which may chemically adsorb a large amount of contaminants. Screening water treatment with bar screen is very essential for etp.

What is Secondary Clarifier Design Tank?

What is Secondary Clarifier Design Tank?

Secondary Clarifier Design Tank

Secondary clarifier design tank  is used in ETP. We use water for many activities, most of which contaminate the water in some Way, i.e. By using detergents, chemicals, dyes t in fabric and yarn in industrial process. This contaminated water is called waste water. Water after usage is called waste water or effluent.

Main use of Secondary Clarifier

  • To Recirculation the Bacteria to the FBBR system
  • To reduce the suspended solids in the effluent
  • To avoided the Bacteria escape to other system
  • To remove the odor in the effluent in secondary clarifier design tank
  • To increase the efficiency of Electrocoagulation system
  • To reduce the current and electrode consumption in EC system
  • To increase the efficiency of FBBR system

Wastewater composition

Wastewater contains approximately 99.0% water and 1% solids maximum.

Expressed in another way, every 1000L of wastewater contains about 10kg of

Solids. The solids are organic and inorganic compounds and are suspended in the

Waste water. Volatile solids are about 70% of the wastewater solids and give the

Water its unpleasant characteristics.

The majority of the solids – carbohydrates, fats and proteins – are broken down

During treatment into more stable inorganic compounds by bacteria and other

Micro-organisms.

Wastewater also contains some compounds that are resistant to normal treatment

Processes, including:

Organics

Fats, oils, grease & organic chemicals

Inorganics

Chlorides, heavy metals, nitrogen, phosphorus and sulphur.

Gases

Hydrogen (H2), sulphide (SO2), methane (CH4) and carbon-di-oxide (CO2).

Effluent treatment plant (etp) capacity

The Effluent treatment plant is designed to treat 2000m3 of Textile dyeing combined

Effluent generated from the process house. The plant will be capable of operating at the flow rate of 100m3/hr. The operating cycle of the plant shall be 20 hours.

Raw effluent characteristics

The effluent treatment plant is designed based on the analysis of effluent analysis report of combined effluent available with us. The relevant parameters are furnished below for your reference.

Parameter value

Ph: 9 -11

Bod: 600 mg/l

Cod: 1300mg/l

Suspended solids: 250mg/l

Total hardness: 50 mg/l

Turbidity: 150ntu

Color: 1000 pt.c0 units

Dissolved oxygen: nil

Tds: 2000 mg/l

After electro coagulation and filteration

Parameter value

Ph: 6.5-7.0

Bod: less than 50ppm

Cod: less than 150ppm.

Suspended solids: less then 5 ppm

Total hardness: 50 ppm

Turbidity: 5 ntu

Color: nil

Effluent treatment plant based on electro-coagulation and fluidized bed bio-reactor technologies.

Treatment steps

  1. Primary treatment
  2. Secondary treatment
  3. Sludge management

Primary treatment

  1. Bar screening
  2. Collection and equalization
  3. Neutralizing
  4. Fluidized bed bioreactor
  5. Secondary clarifier.
  6. Activated sludge recirculation system

Secondary treatment

  1. Electro-coagulation system
  2. Flash mixer
  3. High rate solid content clarifier
  4. Pressure sand filter
  5. Ec cleaning system

Sludge handling

  1. Sludge thickener
  2. Filter press
  3. Sludge storage

Operating cost of etp

Etp tank size and water reserve capacity-

Equalization tank= height-20feet, capacity=2000m3

Fbbr tank= height-17 feet, capacity=1200m3

Secondary clarifier=height-10feet, capacity=0.8m3

Ec feed tank= height-10feet, capacity=60m3

Hrscc tank=height-12feet, capacity=0.8m3

Filter feed tank= height-10feet, capacity-140m3

Sludge tank= height-10feet, capacity-80m3

Total electricity consumption and cost in etp per day-

88 kw per day. Unit price- 89.75 taka/kw

Total cost=7898

Ec plate consumption per day-

Destroyed metal plate per day=254.66 kg.

unit price- 82 taka/kg

total cost= 20882 taka

join coupler used per day= 768 taka

Used chemical and cost per day-

Hcl-125 liter per day. Unit price is -6.60 taka/liter

Total cost= 825 taka

Poly electrolyte-400 gm per day. Unit price is- 1250 taka/kg

Total cost=500 taka

Dap= 5 kg. Unit price is- 33 taka/kg

Total cost=165 taka

Urea=5 kg. Unit price-12 taka/kg

Total cost= 60 taka

Molasses= 10 kg. Unit price is- 36.60 taka/kg

Total cost=366 taka

Total chemical cost per day= 1916 taka.

Man power cost-

Cost per day- 600 taka

Depreciation cost

Total cost- 2, 50, 00, 000 taka

Life time of etp- 10 years

Depreciation cost per day = 6500 taka

Discharge water per day-

32, 40,000 liter per day or 3240 m3

Total cost per day-

38564 taka per day

Cost per liter-

11.90 taka per m3 for secondary clarifier design process

How Sludge Filter Press Pump Works?

How Sludge Filter Press Pump Works?

Sludge Filter Press

A sludge filter press pump is applied to feed the Treated Effluent from Flash mixer with solids & liquids through feed nozzle of the filter press to the chamber formed between the plates and the medium, leaving the solid trapped inside and the liquid drained out. Cake which is build in the hollow space between the plates will fall out once the pack is opened. Filter press is the most efficient and most employed in all filtering process.

Flocculation & Filteration

In the Electrocoagulation process, the Molecular Bonding of the Effluent breaks and the solids are separated and made to more stable form. After Electrocoagulation, An Anionic Poly Electrolyte is dosed from 0.5to 1 mg/L in the Flash Mixer. The Flocculation happens due to this and the bigger size flocs are formed for easier filtration. The Poly Electrolyte is dosed by the Dosing pump which is controlled as per the Flow rate of the Effluent. After the Flash mixer, the Filtration of the solids is done easily by Tube Settler or sludge filter press. The water becomes clear with out suspended solids and Turbidity after this filtration.

Filter Press

A High pressure diaphragm pump is applied to feed the concentrated sludge from high rate solid content clarifier with solids & liquids through feed nozzle of the filter press to the chamber formed between the plates and the medium, leaving the solid trapped inside and the liquid drained out. Cake which is built in the hollow space between the plates will fall out once the pack is opened. Filter press is the most efficient and most employed in all filtering process.

Main Use of Filter Press

  • To get crystal clear water
  • To Separate the sludge and water
  • To make sludge as dry form
  • To achieve the best results in DQO and DBO
  • To remove the Suspended solids

Filter Press Process Description

A High pressure Diaphragm pump is applied to feed the concentrated sludge from high rate solid content clarifier with solids & liquids through feed nozzle of the sludge filter press to the chamber formed between the plates and the medium, leaving the solid trapped inside and the liquid drained out. Cake which is built in the hollow space between the plates will fall out once the pack is opened. Filter press is the most efficient and most employed in all filtering process.

Function: This is a three step process : sludge removal, dewatering and disposal.

Sludge is removed from the HRSCC system from the bottom of sludge recirculation pipe line.

Filter Press
Filter Press

1.Filter Plate; 2 End Plate; 3.Rails ; 4.Hytrolic Jack  5.Plunger; 6 Inlet Pipe; 7.Filterate Discharge Pipe 8.Work Bench

Operation and maintenance consideration 

  • The operator must record it filter press operation time (starting and finishing time of each batch) and no of batches collection from filter press.
  • The operators The desired quantity of polymer needs to be prepared 15-30 minutes before the dewatering operation .
  • The operator After every dewatering operation ,the filter cloths must be thoroughly cleaned. So that clogging in the pores of the woven polypropylene filter fabric is avoided.
  • The operator must clean Every three days once or Periodic cleaning of filter cloth with hydrochloric acid or hypo solution .
  • The operator note When the filtration process becomes excessively slow ,it is time to replace the filter cloth with a fresh set.
  • The operator always maintain stock list of filter cloth.
  • The operator always operate filter press 180 to 260 bar respectively.
  • When the outlet water quality is not good or high turbid content ,change the filter cloth or increases filtration pressure( 180 to 260 bar)

 Trouble shooting

s.noProblemCause
1Filter press does not dewater the slurry sufficientlyPoor maintenance of filter press
2Dewatering is very slowOily /slimy sludge filter press cloth is clogged improper conditioning.
3Insufficient pressure developedRubber stator of screw pump work out.

 

Steel rotor damaged.

The freshly produced cake has a moisture content of between 70-75% .note that it is impossible to achieve a bone –dry cake even after prolonged air-drying; the moisture content would not drop below 50 %.The liquid in the slurry can pass  through the cloth ,while the thickener  paste-like  sludge can not pass through the cloth.

 Maine use of Filter press

  • To remove the moisture content in the final sludge
  • To make sludge as dry form

 Lab tests:

Most of the tests are done in our own laboratory.

Main tests:

  • Ph measurement by digital ph meter
  • Tds measurement by digital tds meter
  • Total solids determination –ts
  • Total dissolved solids determination-tds
  • Total suspended  solids determination -tss
  • Determination of mlss in tss
  • Total hardness
  • Chemical oxygen demand-cod
  • Biochemical oxygen demand-bod
  • Dissolved oxygen-do
  • Turbidity – nt
What is Electrocoagulation Water Treatment System Tank?

What is Electrocoagulation Water Treatment System Tank?

Electrocoagulation Water Treatment System

The electrocoagulation water treatment system process is based on valid scientific principles involving responses of water contaminants to strong electric fields and electrically induced oxidation and eduction reactions. This process is able to take out over 99 percent of some heavy metal cations and also able to precipitate charged colloids and remove significant amounts of other ions, colloids, and emulsions. Electrocoagulation water treatment system is based on the reactive anodes principle. It is a question of generating metallic cations (Al3+ or Fe3+) in wastewater by imposing a D.C. current between the electrodes. These cations act as a coagulant and lead to the destabilization of suspended particles and colloidal structure.

During the treatment, electrolysis reactions between the electrodes make it possible to produce micro bubbles. These finely divided bubbles drag suspended matter with them as they rise to the surface: hydrocarbons, oils, greases and colloids. At the end of the process, treated and decontaminated water is obtained. Electrocoagulation water treatment system is a technology that can be useful to all industries generating mineral or organic pollution. This Technology is ideally suitable for treating Textile Dyes Effluent

electrocoagulation water treatment
Electrocoagulation water treatment

Electrocoagulation is the process of destabilizing suspended, emulsified or dissolved contaminants in an aqueous medium by introducing an electrical current into the medium. The electrical current provides the electromotive force to drive the chemical reactions. When reactions are driven or forced, the elements or compounds will approach the most stable state. Generally, this state of stability produces a solid that is either less colloidal and less emulsified (or soluble) than the compound at equilibrium values. As this occurs, the contaminants form hydrophobic entities that precipitate and can easily be removed by a number of secondary separation techniques.

Electrocoagulation is an Unique and Latest technology successfully implemented in Developed and Developing Countries. The Advantages of electrocoagulation water treatment system ETP are as follows.

No addition of Chemicals, Lime or Ferric.

Very Low Operating Cost.

Less requirement of Space and Civil Construction.

Easy to maintain and operate.

Colour Removal more than 95%.

Electrocoagulation Water Treatment Process

Electrochemical techniques are important for the treatment of Textile   wastewater because they present high efficiency, easy operation and environmental compatibility; this process involves in sit generation of coagulants by electrolytic oxidation of a sacrificial anode (iron) by applying a direct current. The most widely used electrode materials in electro coagulation process are  iron. The hydrolyzed iron  ions can form long chains of Fe-O-Fe-OH which may chemically adsorb a large amount of contaminating .For most applications a proper removal of all impurities ( Physical, biological and Dissolved impurities) of the water reused, is required.

After biological treated water is secondary clarifier  and remove suspended particles and fed in to electrocoagulation water treatment system. The electro coagulation process works at  input feed  PH is 6.0 to 8.0 and conductivity >2000 milligrams/litre. Before and after were monitored for color, turbidity, pH and chemical oxygen demand reduction efficiency. Normally electro coagulation process  reduces  COD  50 to 60 %  from input COD of  electrocoagulation water treatment system process .

Working principle

  • Dissolution of metal ions from an electrode by applied potential.
  • Simultaneous evolution of H2 gas bubbles.
  • Destabilisation of suspension coagulation.
  • H2 bubbles promote flotation, but also sedimentation may occur.
  • Pair(s) of Fe or Al parallel plate electrodes separated by a few mm.

Electrocoagulation Chemical reaction

Electrocoagulation Chemical reaction

Main reactions occurring at the electrodes are:

Electrocoagulation Chemical reaction 1

In addition, Fe3+ and  OH- ions generated at electrode surfaces react in the bulk waste water to form ferric hydroxide:

The iron hydroxide flocs act as adsorbents  and /or traps for pollutants and so eliminate them from solution.

Electrocoagulation Merits

Overall, compared to conventional methods of treating wastewater involving physical and biological processes, electrocoagulation water treatment system is generally considered far more effective in removing pollutant. Not only that, it is also compact and space-saving and while there are arguments in terms of cost calculation, but however, to most experts’ opinion, it is actually cheaper to maintain in the long run.

Electro coagulation process (using iron electrodes) is a reliable, efficient and cost- effective method. quickest removal rate  with the lowest cost.

Before start up EC PROCESS the operator must check EC input effluent PH ,it should be always greater than 6.5 and less than 8.5.

EC operates at PH  6.5 TO 8.5 .

Every day before start up, EC the operator must clean EC skid with HCl. The operator should maintain the PH of the diluted Acid as less than 2.0. If the cleaning acid PH greater than 2.0, must drain old acid(high PH acid > 2.0)  and fill new hydro choleric acid  and clean EC skid.

Every day  The operator’s every one hour once give air circulation in to EC SKID .

Before start EC skid the operator must prepare poly electrolyte dosing chemical.

The operator must  dose poly electrolyte 2 to 2.5 ppm in EC outlet water.

Every day The operator always take chemical stock list and material stock list (EC PLATES ).

If EC plant stop, the operator must drain EC skid water and  well rinse EC SKID with treated water .

Every day the operators note EC voltage and current value and record it separate  log sheet.

The operator every one hours once check EC TREATED WATER QUALITY. if water quality is not good increase current value and set  correct current value. IF treated water more green color present  reduced  EC skid current value and  set correct current value.

Conclusion

Every day once the operator must prepare poly electrocoagulation water treatment system dosing. Normally 5 to 7 days once the operators must change  used cleaning acid   or Acid PH greater than 2.0 change the cleaning acid. When EC PLATE changing  period the operator must note EC plates are sited  in the mounding grid  properly. It is very essential for any textile industry.

What is Activated Sludge Tank and Treatment ?

What is Activated Sludge Tank and Treatment ?

Activated sludge tank

We  selected 210  m3 capacity existing concrete activated sludge tank for bio cultivation process.  Maintained mlss as 3000 mg/litre 7000 mg/litre , do value maximum 4 mg/litre and minimum 1.0 mg/litre., ph  6.5 to 7.9 , sv-30 as 300  to 500 ml/litre, temperature is < 37  degree celsius and constant feed flow rate. Control of the activated sludge tank process is important to maintain a high treatment performance level under a wide range of operating conditions

Activated sludge treatment

BIOLOGICAL PROCESS REACTION

After equalization process using acid to reduce  ph from  9.0 to 6.5. After neutralization process  the effluent   are giving constant feed flow rate 20 m3/hr into bio tank. Here 20 m3 to 24 m3/hr  is re circulated from secondary clarifier   and fed in to bio tank process .the heavy organic solids, gradually fed into biological tank ( capacity 210 m3 ) process containing millions of microorganisms that can only survive and multiply in an environment containing free oxygen that is dissolved in the water and a food source. This method for treating wastewater is referred to as the activated sludge process. Oxygen is provided by pumping and diffusing air (similar to how air is pumped and diffused in a fish aquarium) into large tanks containing the microorganisms and   raw effluent. The mixture of microorganisms, raw  effluent and dissolved oxygen is referred to as mixed liquor suspended solids (mlss). After the aeration period, the mlss is transferred to secondary clarifier, where it is allowed to settle by gravity leaving a clear liquid referred to as  electro coagulation feed effluent . While the settled mlss is returned to the aeration tanks to maintain the appropriate population and cultures of microorganisms. Return of the mlss from secondary m clarifier  tanks to the front of the aeration tanks is referred to as return activated sludge (ras). As the microorganisms multiply, the amount of food available in the raw effluent will become insufficient and the quality of treatment can degrade. . This wasting is referred to as waste activated sludge (was) ,this excess sludge tank fed in to sludge bed and reused ( like natural fertilizer) . After biological process  input  raw  effluent cod reduces minimum50%.

Biological process reaction :

Important maintaince of process:

  • The principal factors in procedure control are the subsequent:
  • Maintenance of dissolved oxygen levels within the aeration tanks.
  • Regulation of an amount of returning activated sludge treatment
  • Control of a waste activated sludge tank

Standard turbidity solution preparation of Activated sludge treatment

Solution aSolution b400ntu

 

 

Take 1 gm of hydrazinium sulfate in 100 ml

 

Volumetric flask

Take 10 gm of hexamethylein tetramine in 100 ml volumetric flaskTake 5 ml solution a & 5 ml solution b in 100 ml volumetric flask
Make up to 100 ml by using dm waterMake up to 100 ml by using dm waterKeep 24 hrs at    25’ c
Make up to 100 ml by using dm water
100 ntu10 ntu
Take  25 ml of 400 ntu solution in 100 ml

 

Volumetric flask

Take  10 ml of100 ntu solution in 100 ml

 

Volumetric flask

Make up to 100 ml by using dm waterMake up to 100 ml by using dm water
Prepare weekly oncePrepare weekly once

Operation procedure

Set zero by using distilled water

Change the range to 0-200

Place test tube of 100 ntu solution

Adjust the display to 100 by using calibrate knob

Check the meter by using 10 ntu solution

Both are correct ,then check the samples

Standardisation of edta solution-1

Burette

x n edta solution

Conical flask

20 ml 0.02n calcium carbonate solution

2-3 drops ammonia buffer solution

Pinch of erio chrome black –t indicator

Titration

0.02n calcium carbonate vs x n edta solution

Endpoint

pink color change to sky blue

Calculation

Normality of edta x =                 20 x 0.02

titrate value

Standardisation of edta solution-2

Burette

X n edta solution

Conical flask

56 mg zinc sulfate dissolved in 10-20 ml distilled water

5 ml ammonia buffer solution

Pinch of erio chrome black –t indicator

Titration

zinc sulfate vs x n edta solution

Endpoint

pink color change to sky blue

Calculation

Normality of edta x =               wt of znso4 x titrate value

287.54 x 1000

Standardisation of sulfuric acid solution

 

 

Titration

BuretteX n sulfuric acid
Conical flask20 ml 0.02n sodium carbonate
IndicatorMethyl orange
Titration valueA1
End pointGolden yellow to red orange

Calculation

Normality of sulfuric acid x =                       20 x 0.02

a1

Standardisation of sodium hydroxide

 

 

Titration

BuretteX n sulfuric acid
Conical flask20 ml y n   sodium hydroxide
IndicatorPhenolphthalein
Titration valueA2
End pointDisappearance of pink color

Calculation

Normality of sodium hydroxide y=                      a2 x x

20

Standardisation of sodium thio sulfate                                                                  solution

Buette

x  n   sodium thio sulfate solution

Conical flask

20ml 0.1 n potassium  dichromate solution

20ml dilute hydrochloric acid

20ml 10% potassium iodide solution

2ml starch indicator

Titration

0.1n potassium dichromate vs x n sodium thio sulfate solution

Endpoint

disappearance of dark blue

Calculation

Normality of sodium thio sulfate x =                  20×0.1

titrate value

Standardisation of ferrous ammonium sulfate                                                                  solution

Burette

X n ferrous ammonium sulfate solution

Conical flask

10ml 0.25 n potassium dichromate solution dilute up to 100 ml by using dm water

30ml conc. Sulfuric acid

10min cooling

2-3 drops ferrion indicator

Titration

0.n potassium dichromate vs x n ferrous ammonium sulfate

Endoint

Bluish green to reddish brown

Calculation

Normality of ferrous ammonium sulfate x =                           10×0.25

titrate value

Standardisation of silver nitrate solution

Burette

x  n silver nitrate solution

Conical flask

20ml 0.028n sodium chloride solution

4-5 drops potassium chromate indicator

Titration

0.028n sodium chloride vs x n silver nitrate solution

Endpoint

Appearance of brick red

Calculation

normality of silver nitrate x       =                         20×0.028

titrate value

Standardisation of potassium permanganate

urette

x n potassium permanganate solution

ical flask

20 ml  0.1n oxalic acid solution

20 ml dilute sulfuric acid solution

Heated to 60^c – 80^c on a wire gauze

Titration

0.1n oxalic acid vs x n potassium permanganate

Endpoint

appearance of pink color

Calculation

Normality of potassium permanganate x =                   20×0.1

titrate value

Advantages of Activated sludge treatment

Efficient removal of cod(50% to 60%) and bod.

Good quality of effluent is obtained.

Compact design of Activated sludge tank